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Specific requirements for the raw materials of silicone rubber and the production of silicone rubber products

1. Requirements for Extrusion-Grade Silicone Compounds

1.1 Formulation Specifications

  • Plasticity range: 200~280; Die swell controlled at 10%~25%
  • Reinforcing filler: Fumed nano silica is preferred. Precipitated silica contains high moisture and tends to cause foaming during hot-air vulcanization, not recommended for high-end food-grade tubing.
  • Structure control agent: Hydroxyl silicone oil is the first choice for platinum-cured systems. Hexamethyldisilazane is commonly used in peroxide-cured grades.

Vulcanization System Classification

  • Food grade (coffee machine water & steam tubing): Platinum addition curing system
     
    Dicumyl peroxide (DCBP) is prohibited, as it generates small molecular substances that migrate under high-temperature steam, causing unpleasant odor.
     
    Di-tert-butyl peroxide (DBPH) is only applicable for non-food-contact structural parts.
  • General industrial extruded strips/cable materials: DCBP curing system for continuous hot-air vulcanization.

1.2 Processing Stability Requirements

  • Anti-scorch property: No premature curing under screw shearing and heating inside the barrel.
  • Low volatile content: Low moisture and low cyclic siloxanes to avoid pinholes and internal bubbles.
  • Good surface forming performance: Resists sharkskin, bamboo defect and melt fracture during high-speed extrusion for smooth surface.
  • Consistent batches: Stable hardness, plasticity and shrinkage rate for long-term dimensional consistency.
  • Low fouling: Non-stick to screws and less carbon accumulation during continuous mass production.

1.3 Typical Physical Properties (Hardness 30~60 Shore A)

Tensile strength ≥7.0 MPa; Tear strength ≥15 kN/m; Elongation at break ≥400%
 
Operating temperature: -60~180℃, short-term resistance up to 200℃ under steam
 
Compression set (175℃ × 22h) ≤35% (critical index for sealing tubing)

2. Requirements for Finished Extruded Silicone Products

2.1 Appearance

  • Smooth inner and outer surfaces; free of sharkskin, scratches, pits, bubbles, pinholes, impurities and color difference.
  • No twisting, uneven wall thickness or bamboo-shaped deformation; transparent tubing free of haze and crystal spots.
  • Clean cutting surface; no delamination for co-extruded multi-layer tubing.

2.2 Dimensional Tolerance (Silicone Tubing Reference)

  • ID / OD standard tolerance: ±0.10~±0.15 mm; Precision food tubing: ±0.08 mm
  • Uniform wall thickness, eccentricity ≤8% (critical for pressure-bearing coffee tubing to prevent rupture)
  • Post-vulcanization shrinkage: 0.8%~1.3%; Shrinkage compensation must be considered in die design.

2.3 Food Contact Specifications (Coffee Machine Silicone Tubing)

  1. Process: Platinum curing + post-curing
     
    Recommended post-curing: 200℃, 4~6 hours, to remove low-molecular D4/D6 cyclic siloxanes, eliminate odor and reduce migration.
  2. Compliance Standards
     
    China: GB 4806.11; Export markets: FDA 21CFR177.2600, LFGB
  3. Sensory requirement: Odor-free. No off-flavor or contamination to coffee after exposure to hot water and steam.
  4. Medium resistance: Resist hot water and saturated steam; No hardening, cracking or bleeding after long-term thermal cycling.

2.4 Mechanical & Durability Performance

  • Thermal cycling resistance: No hardening, cracking or rapid elasticity degradation under repeated temperature cycles (-40℃ ↔180℃).
  • Burst pressure meets design requirements without slow leakage.
  • Aging resistance: Resists yellowing and cracking under long-term humidity and ozone exposure.
  • Good resilience: No permanent deformation after repeated bending during assembly.

2.5 Sanitary Characteristics for Fluid Transport

Low inner surface friction & low absorption, less scale and coffee grease adhesion, easy cleaning.

3. Coordinating Process Notes for Materials & Products

  • Main vulcanization method: Continuous hot-air vulcanization tunnel, temperature range 180~320℃
  • Compounded silicone should be fully cooled and matured with constant-temperature storage; hot compound cannot be extruded directly.
  • Feed continuously with long silicone strips. Fragmented feeding easily entraps air and forms bubbles.
  • Stable traction speed; speed fluctuation directly creates bamboo-shaped dimensional defects.